Chemical elements
  Nitrogen
    Isotopes
    Energy
    Nitrogen Cycle
    Production
    Application
    Physical Properties
      Compressibility
      PV and temperature
      Specific Heats
      Viscosity
      Refractivity
      Spectra
      Solubility
      Liquid Nitrogen
      Solid Nitrogen
      Active Nitrogen
      Formation of Nitrides
      Atomic Weight
      Disintegration
    Chemical Properties
    Ammonia
    Hydroxylamine
    Hydrazine
    Azoimide
    Nitric Acid

Liquid Nitrogen






Cailletet first liquefied nitrogen by compressing it to 200 atmospheres and allowing it to expand rapidly. Liquid nitrogen is colourless, with a refractive index of 1.2053. The critical data of nitrogen, according to different investigators, is given in the following table:

Critical temperature: from -147.13 to -144.7
Critical pressure: from 33.49 to 35.00
Critical density: from 0.31096 to 0.32690

The following table gives the variation of the boiling-point of nitrogen with the pressure:

Variation of the boiling-point of nitrogen with the pressure

Pressure, mm. (Cath.)Absolute Boiling- point.Pressure, Atm. (Crommelin.)Absolute Boiling- point.
120.964.512.50786.21
361.671.547.37099.51
561.374.8321.82117.62
76077.3133.46 crit. pt.125.96
938.679.18
1591.184.21


The empirical formula, giving the vapour pressures of liquid nitrogen at any temperature between -208.36 to -148.08° C., maybe written as:

log p = -510.64/T + 12.381 - 0.12696T + 0.0008302T2 - 0.0000019975T3, where T=t+273.09.

Densities of liquid nitrogen at various temperature

t° C.Density of Liquid.Density of Gas.
-148.080.43140.18620
-149.750.47990.16380
-153.650.53320.11170
-161.200.60710.06987
-173.730.69220.02962
-182.510.74330.01558
-195.090.80430.00490
-200.030.82650.00278
-205.450.84990.00136
-208.360.86220.00089


These values may be compared with those of earlier investigators and with others, from which the following densities (of liquids only) have been selected:

t
-210.5-205-200-198.3-195.5-195.5-190-185-184
d0.87920.85370.83090.82970.81030.80420.78740.76220.7576


The latent heats of evaporation (in calories per gram) are given in the following table:

Latent heat of evaporation of liquid nitrogen

° C-148.08-148.61-149.75-153.65-161.20-173.73-182.51-195.09-200.03-205.45-208.36
T.° abs.125.01124.48123.34119.44111.8999.3690.5878.0073.0667.6464.73
l cals. per gram9.1711.4015.0322.9631.7339.6343.0947.0648.6450.5251.64


These latent heats may be represented by the formula

l2 = 89.962(TC - T) - 1.47242(TC - T)2 + 0.011666(TC - T)3.

The specific heat of liquid nitrogen at -200.4° C., and also at -209° C., is 0.476.


Surface Tension

This was first determined at -196° C. as 8.514 dynes per cm., while the variation with temperature is as follows:

t° C.-203-193-183
γ dynes/cm.10.538.276.16


The change in the molar surface tension with the temperature is given by

r(VM)2/3 = 2.002(124.29 - T),

in which VM is the molar volume M/D.

The temperature coefficient 2.002 is slightly below the mean value for normal liquids. The relation is rectilinear, as usual, up to a temperature a few degrees below the critical temperature (126° to 128° abs.).
© Copyright 2008-2012 by atomistry.com